Abstract

Magnetic hyperfine interactions in (Fe salen C1)2 have been studied using the Mössbauer effect in external magnetic fields up to 80 kOe and for 4.2 ≤ T ≤ 80 °K. The low‐temperature results are adequately described by a simple intramolecular exchange model with J = 7.0 cm−1 and a hyperfine interaction constant of −180 kOe per unit spin. At higher temperature the effective field approximation breaks down. Data for (Fe salen)2O are also briefly reported.

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Physics

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This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Physical Society. The following article appeared in Journal of Chemical Physics.

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URL: http://digitalcommons.calpoly.edu/phy_fac/176