Published in Physical Review Letters, Volume 59, Issue 21, November 23, 1987, pages 2443-2446.
Copyright © 1987 American Physical Society. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Physical Society. The following article appeared in Physical Review Letters and may be found at http://dx.doi.org/10.1103/PhysRevLett.59.2443.
NOTE: At the time of publication, the author Richard B. Frankel was not yet affiliated with Cal Poly.
A combination of magnetic susceptibility and Mössbauer measurements on quasicrystalline i-Al74Mn20-xFexSi6 (0.02≤x≤7.5) establishes that Mn atoms in i-Al74Mn20Si6 occupy two distinct classes of sites, and that Fe substitutes for only one of them. The two classes are distinguished by the possession or otherwise of a localized magnetic moment. The data are consistent with a structure of interconnecting Mackay icosahedra (MI) in which localized moments are possessed only by Mn atoms adjacent to "broken" MI connections. The implied connectivity of the resulting MI network is close to that anticipated for a packing of MI on a three-dimensional Penrose-tile lattice.